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World Journal of Engineering
Research and Technology

( An ISO 9001:2015 Certified International Journal )

An International Peer Reviewed Journal for Engineering Research and Technology

ISSN 2454-695X

Impact Factor : 5.924

ICV : 79.45

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Abstract

STUDY OF STRUCTURAL PROPERTIES AND EFFECT OF SUBSTRATE TEMPERATURE ON OPTICAL PROPERTIES OF SPRAY PYROLYTICALLY DEPOSITED CdZnSe2xTe2(1-x)THIN FILMS FOR X=0.75

Gaikwad S. A.*

ABSTRACT

Spray pyrolysis is a simple, inexpensive and economical method to produce a thin film on large substrate area. Semiconducting thin films of CdZnSe2xTe2(1-x) with composition parameter x=0.75 have been deposited onto preheated glass substrate by varying substrate temperature from 250°C at an interval of 25°C to 325°C. The optimized deposition temperature is around 300°C. From optical transmission and reflection spectra, absorption coefficient(?) was calculated at various wavelengths ranging from 350 nm to 1100 nm and was of the order of 104 cm-1. Band gap energy were determined from absorbance measurement in visible range using Tauc theory. It shows that the main transition at the fundamental absorption edge is a direct allowed transition. At the temperature of 300°C, the optical band gap is found to be 2.47 eV. At the temperatures less than or greater than 300°C, the optical band gap goes on increasing. The refractive index(n) and extinction coefficient(k) both decreases as wavelength increases which shows that the optical constants are most suitable for many scientific studies and technological applications such as heat mirrors, transparent electrodes and solar cells. SEM study provide the information regarding the morphology of the material which confirms the formation of nano sized, nanotubes. From the TEM study it is clear that formation of crystals is cubic in nature which is also confirmed from XRD studies. The value of lattice parameter „a? is 6.1451 A° for CdZnSe2xTe2(1-x) thin films deposited at substrate temperature 300°C with composition parameter „x=0.75.?

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